Measurements have been made of the concentration dependence of the rise and decay time characteristics of the monomer and excimer fluorescence of deoxygenated solutions of pyrene in cyclohexane at temperatures from 293 to 340 °K. This text was harvested from a scanned image of the original document using optical character recognition (OCR) software. 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Excimer formation and … If the address matches an existing account you will receive an email with instructions to reset your password. Please contact the Royal Society if you find an error you would like to see corrected. The longer component had a value of about 100 ns. Hence the pyrene fluorescence is very susceptible to energy transfer quenching by impurities having shorter excited lifetimes, with a conse-quent reduction in TD. Therefore, it is produced in a wide range of combustion conditions. Show Policy, Bulletin of the Chemical Society of Japan, PDF In conjunction with observations of the monomer and excimer fluorescence quantum efficiencies, the results have been analyzed to determine the six rate parameters which describe the behaviour of the system. 1Division of Chemistry, Research Institute of Applied Electricity, Hokkaido University. Nakajima Akira 1. Pyrene has been used for more than 50 years as fluorescent probe par excellence for microheterogeneous systems such as micelles,,,,,,,,,,,,, polymers,,, proteins,,, peptides … As shown in the intensity decay figure, the fluorescence lifetime, t, is the time at which the intensity has decayed to 1/e of the original value. Enter your email address below and we will send you your username, If the address matches an existing account you will receive an email with instructions to retrieve your username. Please login to view your saved searches. B. BIRKS, D. J. DYSON AND I. H. MUNRO The Physical Laboratories, University of Manchester (Communicated by B. H. Flowers, F.R.S.-Received 26 April 1963) Measurements have been made of … Here, we need only be concerned with excimer formation and decay. From the difference in the activation energies for excimer dissociation and formation, the excimer binding energy is found to be 0.34eV. Fluorescence lifetime measurements for pyrene co‐deposited with HEX, OCT and SA on acid‐washed sand, measured at wavelengths corresponding to primarily monomer emission (380 nm) and primarily excimer emission (500 nm), are presented in the Supporting information, along with a tentative kinetic analysis. Our journal website uses cookies to support your experience . Fluorescence Lifetime of Pyrene in Different Solvents. Fluorescence of the protein adducts exhibited two distinct lifetimes for each adduct. For example, automobiles produce about 1 μg/km. Pyrene was first isolated from coal tar, where it occurs up to 2% by weight. Fluorescence Enhancement of Pyrene Chromophores Induced by Alkyl Groups through σ–π Conjugation: Systematic Synthesis of Primary, Secondary, and Tertiary Alkylated Pyrenes at the 1, 3, 6, and 8 Positions and Their Photophysical Properties. Fluorescence Lifetime of Pyrene in Different Solvents. As such, it may contain errors. As a peri-fused PAH, pyrene is much more resonance-stabilized than its five-member-ring containing isomer fluoranthene. Two independent methods were employed, one using a pulsed light source and a pulse-sampling oscilloscope, and the other a modulated light source and a phase and modulation fluorometer. Lifetime studies of pyrene solutions. Excimer formation is shown to be a diffusion-controlled collision process, in which every collision between excited and unexcited molecules is effective. Values of 6.8 x 10-7 and 0.9 x 10-7s are obtained for the radiative lifetimes of the monomer and excimer, respectively. The fluorescence decay time of pure pyrene (113 ns at room temperature) is long compared with that of other aromatic hydrocarbons. Measurements have been made of the concentration dependence of the rise and decay time characteristics of the monomer and excimer fluorescence of deoxygenated solutions of pyrene in cyclohexane at temperatures from 293 to 340 °K. purities in the specimens with lower values of TD. … Enter your email address below and we will send you the reset instructions. Because of the long lifetime, N-(3- pyrene)maleimide is useful for fluorescence polarization studies of high molecular weight proteins and other macro- Lifetime studies of pyrene solutions BY J. 1973, Vol.46, No.8. Scanned images copyright © 2017, Royal Society, 'Excimer’ fluorescence II. 'Excimer' fluorescence II. Open Access. 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